Methanolysis of Crude Jatropha Oil using Heterogeneous Catalyst from the Seashells and Eggshells as Green Biodiesel


heterogeneous catalyst
alternative green energy resource


In this work, heterogeneous calcium oxide catalysts gleaned from Polymedosa expansa and eggshell were investigated for the transesterification of crude jatropha oil with methanol, to access their prospective performance in biodiesel production as an alternative green energy resource. The best yield of biodiesel achieved was 96% in 1 h for Step 1 using 0.01:1 ratio of acid catalyst to oil and 0.6:1 ratio of alcohol to oil ratio, together with 2 h of Step 2 using 0.02:1 ratio with base catalyst CaO, derived from P. expansa, to oil ratio and 5:1 ratio of alcohol to oil.  The properties of jatropha biodiesel were analyzed and found to have calorific value of 35.43 MJ/kg, density value of 895 kg/m3 and flash point of 167. The biodiesel was blended with mineral diesel from B0 to B50 for a diesel engine performance test. B20 indicated comparable characteristics with pure mineral diesel, like lowest fuel consumption rate, specific fuel consumption rate, highest brake horsepower and mechanical efficiency.


Azhari, M, Yunus, FR, Mohd. Ghazi, TI & Yaw TCS 2008, ‘Reduction of free fatty acids in crude Jatropha Curcas oil via an esterification process’, International Journal of Engineering and Technology, vol. 5, no. 2, pp. 92–98.

Azimah, AR, Mohd Hanafi, I, Abu, HMK, Wong, SK & Arshad, A 2012, ‘Analysis of condition index in Polymesoda expansa (Moussson 1849)’ Pak. J. Biol. Sci., vol. 15, no. 13, pp. 629–634.

Bachok, Z, Mfilinge, PL & Tsuchiya, M 2003, ‘The diet of the mud clam Geloina coaxans (Mollusca, Bivalvia) as indicated by fatty acid markers in a subtropical mangrove forest of Okinawa, Japan,’ Journal of Experimental Marine Biology and Ecology, vol. 292, no. 2, pp. 187–197.

Bobade, SN, Kumbhar, RR & Khyade VB 2013, ‘Preparation of methyl ester (biodiesel) from Jatropha curcas Linn oil’, Research Journal of Agriculture and Forestry Sciences, vol. 1, no. 2, pp. 12–19.

Bojan, SG & Durairaj SK 2012, ‘Producing biodiesel from high free fatty acid Jatropha curcas oil by a two step method — an Indian case study’, Journal of Sustainable Energy & Environment, vol. 3, pp. 63–66.

Buasri, A, Chaiyut, N, Loryuenyong, V, Wongweang, C & Khamsrisuk, S 2013, ‘Application of eggshell wastes as a heterogeneous catalyst for biodiesel production’, Sustainable Energy, vol. 1, no. 2, pp. 7–13.

Chung, KH, Chang, DR & Park, BG 2008, ‘Removal of free fatty acid in waste frying oil by esterification with methanol on zeolite catalysts’, Bioresource Technology, vol. 99, pp. 7438–7443.

Cluzel, C 2013, The role of biofuels beyond 2020, BP, Element Energy Limited, Cambridge.

Demirbas A, 2009, ‘Progress and recent trends in biodiesel fuels’, Energy Conversion and Management, vol. 50, no. 1, pp. 14–34.

Deng X, Fang Z & Liu YH 2010, ‘Ultrasonic transesterification of Jatropha curcas L. oil to biodiesel by a two-step process’, Energy Conversion Management, vol. 51, pp. 2802–2807.

Gubitz, GM, Mittelbach, M, Trebi, M & Trabi, M 1999, ‘Exploitation of tropical oil seed plant Jatropha Curcas L.’, Bioresource Technology, vol. 67, pp. 73–82.

Gui, MM, Lee, KT & Bhatia, S. 2008, ‘Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock’, Energy, vol. 33, pp. 1646–1653.

Srithar, K, Balasubramanian, KA, Pavendan, V & Kumar, BA 2014, ‘Experimental investigations on mixing of two biodiesels blended with diesel as alternative fuel for diesel engines’, Journal of King Saud University – Engineering Sciences,

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Koh, MY & Chazi, TI 2011, ‘A review of biodiesel production from Jatropha Curcas L. oil’, Renewable and Sustainable Energy Reviews, vol. 15, no. 5, pp. 2240–2251.

Leung, YCD, Wu, X & Leung, MKH 2010, ‘A review on biodiesel production using catalyzed transesterification’, Applied Energy, vol. 87, no. 4, pp. 1083–1095.

Lippke, B, Gustafson, R, Venditti, R, Volk, T, Oneil, E, Johnson, L, Puettmann, M & Steele, P 2011, ‘Sustainable biofuel contributions to carbon mitigation and energy independence’, Forests, vol. 2, pp. 861–874.

Marchetti, JM, Miguel, VU & Errazu, AF 2007, ‘Possible methods for biodiesel production,’ Renewable and Sustainable Energy Reviews, vol. 11, no. 6, pp. 1300–1311.

Meher, LC, Churamani, CP, Arif, M, Ahmed, Z & Nail, SN 2013, ‘Jatropha curcas as a renewable source for bio-fuel-A review’, Renewable and Sustainable Energy Reviews, vol. 26, pp. 397–407.

Mofijur, M, Masjuki, HH, Kalam, MA, Hazrat, MA, Liaquat, AM, Shahabuddin, M & Varman, M 2012, ‘Prospects of biodiesel from Jatropha in Malaysia’, Renewable and Sustainable Energy Reviews, vol. 16, pp. 5007–5020.

Mustakimah, M, Suzana, Y & Maitra, S 2012, ‘Decomposition study of calcium carbonate in cockle shell’, Journal of Engineering Science and Technology, vol. 7, no. 1, pp.1–10.

Nahar, K & Ozores-Hampton, M 2011, ‘Jatropha: an alternative substitute to fossil fuel’, Horticultural Sciences Departments Florida: Institute of Food and Agriculture Science, University of Florida, pp. 1–9.

Qien, JF, Shi, HX & Zhi, T 2010, ‘Preparation of biodiesel from Jatropha curcas L. oil produced two-phase solvent extraction’, Biosource Technology, vol. 101, no. 18, pp. 7025–7031.

Ismail, S, Abu, SA, Rezaur, R & Sinin, H 2014, ‘Biodiesel production from castor oil and its application in diesel engine’, ASEAN J. Sci. Technol. Dev., vol. 31, no. 2, pp. 91–101.

Said, N, Fatimah, A, Misebah, Siti FH, Nur, SG, Rosli, MY & Gimbun, J 2014, ‘Activated Paphia undulata shells waste (APSW): a cost-effective catalyst for biodiesel synthesis from rubber and Jatropha curcas seeds oil (RSOME & JSOME)” International Journal of Chemical Engineering and Applications’, vol. 5, no. 6, pp. 483–488.

Edin, T, Ahmed, AS, Rahman, R & Hamdan, S 2013, ‘Biodiesel production from jatropha oil as an alternative fuel for diesel engine’, Journal of Energy & Environment, pp. 18–24.

Yang, CY, Deng, X, Fang, Z & Peng, DP 2010,‘Selection of high oil yield seed sources of Jatropha curcas L. for biodiesel production’, Biofuels, vol. 1, pp. 705–717.


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